The cartoon is slated to air Sunday on Hub TV.
Hov will play himself, a self-made business and music mogul who gives four students some sound advice and encouragement to pursue their dreams.
Secret Millionaires Club will also feature one of America's most accomplished investors Warren Buffet, whose character helps kids learn about "investing in yourself."
Buffet plays an adviser to a group of entrepreneurial students who go through trials to learn the basic principles about business. The debut episode is titled Be Cool to Your School. Check out a snippet featuring Jay-Z below.