5. Better First Kiss
"The Amazing Spider-Man" never had a chance in this category. Peter Parker's playful reveal of his powers to Gwen Stacy and subsequent smooch is some nifty film making, but the upside-down embrace in the rain between Tobey Maguire and Kirsten Dunst in the original instantly achieved iconic status, and stands as one of the most memorable moments in the history of superhero cinema. Even if you hated "Spider-Man," it was hard to hate that kiss. Winner: "Spider-Man"