The actress was previously wed to retired NFL running back Chris Howard.
Other first-time nominees include Pau Gasol, Tony Parker, Gregg Popovich, and the 1976 U.S. Women's Olympic Team.
Siohvauhgn Funches-Wade alleges the NBA champion "may be pressuring" their child.
The Wades had an eventful birthday celebration for Union while in South Africa.
The NBA retiree has addressed the allegations leveled against him by his ex-wife.
The former NBA baller has filed to change his daughter's gender and name on her birth certificate.
The program premieres on October 7th.
The Dwyane Wade and Lebron James executive-produced film arrives this fall.